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Accurate quantification of uncertainty in solar photovoltaic (PV) generation forecasts is imperative for the efficient and reliable operation of the power grid. In this paper, a data-driven non-parametric probabilistic method based on the Naïve Bayes (NB) classification algorithm and Dempster–Shafer theory (DST) of evidence is proposed for day-ahead probabilistic PV power forecasting. This NB-DST method extends traditional deterministic solar PV forecasting methods by quantifying the uncertainty of their forecasts by estimating the cumulative distribution functions (CDFs) of their forecast errors and forecast variables. The statistical performance of this method is compared with the analog ensemble method and the persistence ensemble method under three different weather conditions using real-world data. The study results reveal that the proposed NB-DST method coupled with an artificial neural network model outperforms the other methods in that its estimated CDFs have lower spread, higher reliability, and sharper probabilistic forecasts with better accuracy.